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dc.contributor.authorSignorini, Virginia
dc.contributor.authorAnsaloni, Luca
dc.contributor.authorPeters, Thijs
dc.contributor.authorAlcock, Benjamin
dc.contributor.authorGiacinti Baschetti, Marco
dc.contributor.authorMinelli, Matteo
dc.identifier.citationACS Applied Polymer Materials. 2023, 6 (1), 379-389.en_US
dc.description.abstractCarbon capture and storage (CCS) is one of the most viable solutions to limit the CO2 emission in the atmosphere, with the potential to be applied at short-medium time scales. In this concern, polymeric materials play a relevant role in protecting equipment in the CO2 transport value chain (such as pipelines, pumps, vessels, or compressors). Among the various classes of polymers, fluorinated materials look promising for such application due to their excellent thermal and chemical resistance, combined with a favorable interaction with CO2 in its supercritical or in a liquid state. This work explores the sorption, diffusion, and permeation properties of various fluorinated thermoplastic polymers when exposed to high-pressure carbon dioxide. Furthermore, the obtained results are analyzed by a thermodynamic equation of state (EoS) to describe the solubility behavior, while the standard transport model (STM) provides a reliable representation of gas transport. That allows the understanding of the penetrant–polymer interaction and the effect of dense phase CO2 on polymer-based materials in a wide range of temperatures and pressures. The comparison of sorption and transport data by means of the dedicated model allows the reliable prediction of the effects of CO2 on such fluorinated polymers at all desired temperature and pressure ranges, relevant for CO2 transport (e.g., dense phase CO2, up to supercritical conditions).en_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsNavngivelse 4.0 Internasjonal*
dc.titleCharacterization and Modeling of CO2 Transport through Fluorinated Thermoplasticsen_US
dc.title.alternativeCharacterization and Modeling of CO<inf>2</inf> Transport through Fluorinated Thermoplasticsen_US
dc.typePeer revieweden_US
dc.typeJournal articleen_US
dc.rights.holder© 2023 The Authors. Published by American Chemical Society.en_US
dc.source.journalACS Applied Polymer Materialsen_US

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Navngivelse 4.0 Internasjonal
Except where otherwise noted, this item's license is described as Navngivelse 4.0 Internasjonal