dc.contributor.author | Pollen, Harald Norrud | |
dc.contributor.author | Tolchard, Julian R | |
dc.contributor.author | Svensson, Ann Mari | |
dc.contributor.author | Wagner, Nils Peter | |
dc.date.accessioned | 2023-01-24T09:55:03Z | |
dc.date.available | 2023-01-24T09:55:03Z | |
dc.date.created | 2022-11-07T09:30:07Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | ChemElectroChem. 2022, 9 (19), 1-12. | en_US |
dc.identifier.issn | 2196-0216 | |
dc.identifier.uri | https://hdl.handle.net/11250/3045739 | |
dc.description.abstract | In this work we report variations of LiNi0.88Mn0.06Co0.06O2 synthesised through a single-pot oxalic acid co-precipitation route, in which all cation precursors were added in the same step. The effects of Al-doping, heat-treatment temperature and Li precursor excess were investigated with physicochemical and electrochemical characterisation. Phase pure and well-ordered polycrystalline materials were successfully synthesised for all Al-doped and undoped compositions. Undoped LiNi0.88Mn0.06Co0.06O2 prepared at 750 °C with 4 at% excess Li precursor showed excellent cycling stability in NMC||LTO cells with an initial capacity of 201 mAh/g at 0.1 C at 20 °C, and a capacity retention of 81 % after 415 cycles. The Al-doped variations LiNi0.88Mn0.04Co0.06Al0.02O2 and LiNi0.88Mn0.06Co0.04Al0.02O2 were synthesised, and they showed similar initial electrochemical performance to undoped LiNi0.88Mn0.06Co0.06O2, but Al-doping via the oxalic acid co-precipitation route resulted in shorter cycle life. The study outlines the importance of the processing parameters to achieve Ni-rich layered oxides with a long cycle life without further surface modifications. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | European Chemical Societies published by Wiley-VCHGmbH | en_US |
dc.rights | Navngivelse-Ikkekommersiell 4.0 Internasjonal | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/deed.no | * |
dc.title | A Single-Pot Co-Precipitation Synthesis Route for Ni-Rich Layered Oxide Materials with High Cycling Stability | en_US |
dc.title.alternative | A Single-Pot Co-Precipitation Synthesis Route for Ni-Rich Layered Oxide Materials with High Cycling Stability | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | © 2022 The Authors.ChemElectroChem published by Wiley-VCHGmbH | en_US |
dc.source.pagenumber | 1-12 | en_US |
dc.source.volume | 9 | en_US |
dc.source.journal | ChemElectroChem | en_US |
dc.source.issue | 19 | en_US |
dc.identifier.doi | 10.1002/celc.202200859 | |
dc.identifier.cristin | 2069729 | |
dc.relation.project | Norges forskningsråd: 280910 | en_US |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |