dc.contributor.author | Johnsen, Sverre Gullikstad | |
dc.date.accessioned | 2022-08-16T10:14:20Z | |
dc.date.available | 2022-08-16T10:14:20Z | |
dc.date.created | 2022-01-21T08:13:43Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Fluid Phase Equilibria. 2022, 556 1-14. | en_US |
dc.identifier.issn | 0378-3812 | |
dc.identifier.uri | https://hdl.handle.net/11250/3012059 | |
dc.description.abstract | The solubility of a ”heavy” alkane (solute) in a ”light” alkane (solvent) is generally temperature dependent. Moreover, it is determined by the molar masses of the solute and solvent. In the current paper, published solubility data for binary normal-alkane mixtures is reviewed (solid-liquid equilibrium). A total of 43 unique solute-solvent data-sets, obtained from a total of 24 published experimental studies, are collected and presented in a systematic manner. Based on thermodynamic considerations and the experimental data, it is demonstrated that there is a log-linear relationship between the solubility and the temperature in the dilute range. Linear regression is employed to 1) obtain data-set-specific solubility-temperature best-fit parameters and 2) obtain a general correlation between the solubility and the solvent and solute molar masses and the temperature. Finally, it is demonstrated that the developed correlation carries predictive power even for multi-component mixtures by utilizing solvent and solute average molar masses. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.rights | Navngivelse 4.0 Internasjonal | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/deed.no | * |
dc.subject | Solid-liquid equilibrium | en_US |
dc.subject | Solubility | en_US |
dc.subject | Precipitation | en_US |
dc.subject | Paraffin | en_US |
dc.subject | Alkane | en_US |
dc.title | A Review of Experimental Solubilities and a General Correlation between the Temperature-Dependent Solubility and Solute and Solvent Molar Masses for Binary n-Alkane Mixtures | en_US |
dc.title.alternative | A Review of Experimental Solubilities and a General Correlation between the Temperature-Dependent Solubility and Solute and Solvent Molar Masses for Binary n-Alkane Mixtures | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | © 2022 The Author(s). Published by Elsevier B.V. | en_US |
dc.source.pagenumber | 1-14 | en_US |
dc.source.volume | 556 | en_US |
dc.source.journal | Fluid Phase Equilibria | en_US |
dc.identifier.doi | 10.1016/j.fluid.2022.113380 | |
dc.identifier.cristin | 1987044 | |
dc.source.articlenumber | 113380 | en_US |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 2 | |