dc.contributor.author | Larring, Yngve | |
dc.contributor.author | Pishahang, Mehdi | |
dc.contributor.author | Tolchard, Julian R | |
dc.contributor.author | Lind, Anna Maria | |
dc.contributor.author | Sunding, Martin Fleissner | |
dc.contributor.author | Stensrød, Ruth Elisabeth | |
dc.contributor.author | Jacobs, Marijke | |
dc.contributor.author | Snijkers, Frans | |
dc.contributor.author | van der Kolk, Tjalling | |
dc.contributor.author | Albertsen, Knuth | |
dc.date.accessioned | 2020-11-24T12:52:13Z | |
dc.date.available | 2020-11-24T12:52:13Z | |
dc.date.created | 2020-01-06T11:08:42Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Journal of thermal analysis and calorimetry (Print). 2019, 1-13. | en_US |
dc.identifier.issn | 1388-6150 | |
dc.identifier.uri | https://hdl.handle.net/11250/2689354 | |
dc.description.abstract | The CLOU performance of the CaTixMn0.9-xMg0.1O3 (CMTM) perovskite-type system was investigated, comparing
materials produced at laboratory scale with those made at industrial ton scale. The CLOU and conversion performances
were studied by a micropacked bed reactor, and crystalline phase structure and homogeneity and bulk density identified as
the most important parameters affecting the performance of the OCM. Bulk density is correlated with the sintering
temperature, atmosphere and time at sintering temperature, while phase homogeneity is a function of the raw materials
chosen, agglomeration method and sintering procedure. Specific challenges are identified in the control of slurry homogeneity and sintering conditions in upscaled production. The degree of sintering affects the chemo-mechanical properties of
the material (crushing strength and attrition index), physical properties (specific surface area), and more importantly the
crystalline phases formed and their homogeneity: the quantity of ‘‘active’’ crystalline phases present directly determines the
thermochemical conversion properties (i.e., CLOU capacity and methane conversion), oxygen transfer capacity and
kinetics | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer | en_US |
dc.relation.uri | https://link.springer.com/content/pdf/10.1007%2Fs10973-019-08860-y.pdf | |
dc.subject | SEM | en_US |
dc.subject | In situ XRD | en_US |
dc.subject | Micropacked bed | en_US |
dc.subject | TPX | en_US |
dc.subject | CLOU | en_US |
dc.subject | CLC | en_US |
dc.subject | Sintering temperature | en_US |
dc.subject | CaMnO3 | en_US |
dc.subject | Calcium manganite | en_US |
dc.title | Fabrication process parameters significantly affect the perovskite oxygen carriers materials (OCM) performance in chemical looping with oxygen uncoupling (CLOU) | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | Copyright: The Author(s) 2019 | en_US |
dc.source.pagenumber | 577–589 | en_US |
dc.source.volume | 140 | en_US |
dc.source.journal | Journal of thermal analysis and calorimetry (Print) | en_US |
dc.identifier.doi | 10.1007/s10973-019-08860-y | |
dc.identifier.cristin | 1766672 | |
dc.relation.project | EC/FP7/608571 | en_US |
cristin.unitcode | 7401,80,62,0 | |
cristin.unitcode | 7401,80,40,0 | |
cristin.unitname | Bærekraftig energiteknologi | |
cristin.unitname | Prosessteknologi | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |