dc.contributor.author | Mondino, Giorgia | |
dc.contributor.author | Spjelkavik, Aud I. | |
dc.contributor.author | Nord, Lars O. | |
dc.contributor.author | Krishnamurthy, Shreenath | |
dc.contributor.author | Didriksen, Terje | |
dc.contributor.author | Stensrød, Ruth Elisabeth | |
dc.contributor.author | Grande, Carlos Adolfo | |
dc.contributor.author | Blom, Richard | |
dc.date.accessioned | 2020-06-17T12:41:13Z | |
dc.date.available | 2020-06-17T12:41:13Z | |
dc.date.created | 2020-04-21T13:27:06Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Industrial & Engineering Chemistry Research. 2020, 59 (15), 7198-7211. | en_US |
dc.identifier.issn | 0888-5885 | |
dc.identifier.uri | https://hdl.handle.net/11250/2658491 | |
dc.description.abstract | Well-shaped 300–700 μm spheres of aggregated metal–organic framework CPO-27-Ni crystallites have been produced using a spray-granulation method with cross-bonded alginate as the binder. The spheres are suitable for use in a moving-bed temperature-swing adsorption (MBTSA) process for postcombustion CO2 capture. The adsorption isotherm data of CO2, N2 ,and H2O have been measured in the temperature intervalof 30–120 °C, and adsorption kinetics have been estimated from breakthrough measurements. The adsorption data together with the physical characteristics of the spheres (pore-size distribution and porosity) have been used to simulate the performance of a MBTSA process utilizing the CPO-27-Ni/alginate spheres as adsorbent and compared to similar simulations using Zeolite 13X spheres. Simulations have been carried out in a natural gas-fired power plant (NGCC) context. The process simulations indicate that the net electric efficiency of the NGCC plant with a MBTSA process utilizing the CPO-27-Ni/alginate spheres is similar to that of a MBTSA process utilizing Zeolite 13X adsorbent, 56.1% and 55.9%, respectively, which are slightly higher than the net efficiency of the benchmark case NGCC with a MEA-based solvent process of 54.7%. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | Navngivelse 4.0 Internasjonal | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/deed.no | * |
dc.subject | CO2 capture | en_US |
dc.subject | Adsorption | en_US |
dc.title | Production of MOF Adsorbent Spheres and Comparison of Their Performance with Zeolite 13X in a Moving-Bed TSA Process for Postcombustion CO2 Capture | en_US |
dc.type | Journal article | en_US |
dc.type | Peer reviewed | en_US |
dc.description.version | publishedVersion | en_US |
dc.rights.holder | This is an open access article published under a Creative Commons Attribution (CC-BY)
License, which permits unrestricted use, distribution and reproduction in any medium,
provided the author and source are cited. | en_US |
dc.source.pagenumber | 7198-7211 | en_US |
dc.source.volume | 59 | en_US |
dc.source.journal | Industrial & Engineering Chemistry Research | en_US |
dc.source.issue | 15 | en_US |
dc.identifier.doi | https://doi.org/10.1021/acs.iecr.9b06387 | |
dc.identifier.cristin | 1807327 | |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 2 | |