Blar i SINTEF Open på forfatter "Chen, De"
-
Cluster-size-dependent interaction between ethylene and CuCl2 clusters supported via γ-alumina
Qi, Yanying; Fenes, Endre; Ma, Hongfei; Wang, Yalan; Rout, Kumar Ranjan; Fuglerud, Terje; Marco, Piccinini; Chen, De (Peer reviewed; Journal article, 2020)Alumina-supported copper chloride serves as an industrial catalyst for ethylene oxychlorination, resulting from its high activity and selectivity. A better understanding of the detailed active site structure and reaction ... -
Critical review of catalysis for ethylene oxychlorination
Ma, Hongfei; Wang, Yalan; Qi, Yanying; Rout, Kumar Ranjan; Chen, De (Peer reviewed; Journal article, 2020)Ethylene oxychlorination is the key technology in vinyl chloride (VCM, the monomer of PVC, polyvinyl chloride) production to close the chlorine loop by consuming the HCl released from the former cracking step. Due to the ... -
Development of Polyethylenimine (PEI)-impregnated mesoporous carbon spheres for low-concentration CO2 capture
Chen, Qingjun; Wang, Siyu; Rout, Kumar Ranjan; Chen, De (Peer reviewed; Journal article, 2020)A novel low-concentration CO2 capture material (PEI/MCS) was developed by loading polyethylenimine (PEI) over mesoporous carbon spheres (MCS) with high porosity. The effects of pore structure, PEI loading, capture temperature, ... -
Effect of oxide additives on the hydrotalcite derived Ni catalysts for CO2 reforming of methane
Niu, Juntian; Liland, Shirley Elisabeth; Yang, Jia; Rout, Kumar Ranjan; Ran, Jingyu; Chen, De (Peer reviewed; Journal article, 2018)Here we provide new mechanistic and kinetic insights into the functions of oxides on Ni catalysts in methane dry reforming combining kinetic studies with density functional theory (DFT) calculations. Hydrotalcite derived ... -
Effect of trace potassium on hydrogen adsorption and dissociation on hcp cobalt: A density functional theory study
Chen, Qingjun; Svenum, Ingeborg-Helene; Gavrilovic, Ljubisa; Chen, De; Blekkan, Edd Anders (Journal article; Peer reviewed, 2018)Trace amounts of potassium (K) have a significant influence on the activity and selectivity of cobalt-based catalysts in Fischer–Tropsch synthesis (FTS), in which hydrogen adsorption and dissociation is one of the initial ... -
Effects of metal dusting relevant exposures of alloy 601 surfaces on carbon formation and oxide development
Guo, Xiaoyang; Vanhaecke, Estelle Marie M.; Vullum, Per Erik; Ma, Jianyu; Panditha Vidana, Daham Sanjaya Gunawardana; Walmsley, John; Chen, De; Venvik, Hilde Johnsen (Peer reviewed; Journal article, 2020)Ni and Fe are excellent catalysts for carbon formation, and industrial alloys are therefore susceptible to metal dusting corrosion; a costly issue in e.g. synthesis gas manufacture. The objective of this work is to better ... -
Enhancing capacitance of supercapacitor with both organic electrolyte and ionic liquid electrolyte on a biomass-derived carbon
Wang, Xuehang; Li, Yahao; Lou, Fengliu; Buan, Marthe Emelie Melandsø; Sheridan, Edel; Chen, De (Peer reviewed; Journal article, 2017)Supercapacitor (SC) with organic electrolyte or ionic liquid (IL) electrolyte can generally store/release higher energy than that with an aqueous electrolyte, due to a larger operating voltage window of a non-aqueous ... -
Jet fuel range hydrocarbon production from propanal: Mechanistic insights into active site requirement of a dual-bed catalyst
Yeboah, Isaac; Feng, Xiang; Wang, Gang; Rout, Kumar Ranjan; Cai, Zhenping; Duan, Xuezhi; Zhou, Xinggui; Chen, De (Peer reviewed; Journal article, 2020)Utilization of sustainable biomass to produce jet fuel range hydrocarbons is imperatively needed to mitigate CO2 emissions and to liberate the over-reliance on fossil resources. Using propanal as the feedstock, an excellent ... -
Kinetic modeling of dynamic changing active sites in a Mars-van Krevelen type reaction: Ethylene oxychlorination on K-doped CuCl2/Al2O3
Ma, Hongfei; Sollund, Erling S.; Zhang, Wei; Fenes, Endre; Qi, Yanying; Wang, Yalan; Rout, Kumar Ranjan; Fuglerud, Terje; Piccinini, Marco; Chen, De (Peer reviewed; Journal article, 2020)A kinetic model was developed by taking into account the dynamic nature of the active sites in Mars–van Krevelen type catalytic reactions to predict the evolution of the reactant and product composition in the gas phase ... -
Modified Dolomite-Based Pellets for High Temperature Post-Combustion Co2 Capture
Moral, Ainara; Wold, Anne Charlotte; Rout, Kumar Ranjan; Chen, De (SINTEF Proceedings;7, Chapter; Peer reviewed; Conference object, 2021)In this study, synthetic dolomite-based pellets were prepared by means of one-pot method. Zr and Ce were used as modifier and aluminate cement was employed as binder. The addition of the promoters by two different routes ... -
Selective Charging Behavior in an Ionic Mixture Electrolyte- Supercapacitor System for Higher Energy and Power
Wang, Xuehang; Mehandzhiyski, Aleksandar Yordanov; Arstad, Bjørnar; Van Aken, Katherine L.; Tyler S., Mathis; Gallegos, Alejandro; Tian, Ziqi; Ren, Dingding; Sheridan, Edel; Grimes, Brian Arthur; Jiang, De-en; Wu, Jianzhong; Gogotsi, Yury; Chen, De (Peer reviewed; Journal article, 2017)Ion–ion interactions in supercapacitor (SC) electrolytes are considered to have significant influence over the charging process and therefore the overall performance of the SC system. Current strategies used to weaken ionic ... -
Selective Charging Behavior in an Ionic Mixture Electrolyte- Supercapacitor System for Higher Energy and Power
Wang, Xuehang; Mehandzhiyski, Aleksandar Yordanov; Arstad, Bjørnar; Van Aken, Katherine L.; Tyler S., Mathis; Gallegos, Alejandro; Tian, Ziqi; Ren, Dingding; Sheridan, Edel; Grimes, Brian Arthur; Jiang, De-en; Wu, Jianzhong; Gogotsi, Yury; Chen, De (Peer reviewed; Journal article, 2017)Ion–ion interactions in supercapacitor (SC) electrolytes are considered to have significant influence over the charging process and therefore the overall performance of the SC system. Current strategies used to weaken ionic ... -
Tandem hydrodeoxygenation catalyst system for hydrocarbons production from simulated bio-oil: Effect of C-C coupling catalysts
Yeboah, Isaac; Li, Yahao; Rajendran, Kishore; Rout, Kumar Ranjan; Chen, De (Peer reviewed; Journal article, 2021)Research in the sustainable conversion of biomass to fuels and chemicals is a necessity for the reduction of the carbon footprint in transport energy. Herein, we demonstrate an efficient tandem catalyst to selectively ... -
Understanding of K and Mg co-promoter effect in ethylene oxychlorination by operando UV–vis-NIR spectroscopy
Ma, Hongfei; Fenes, Endre; Qi, Yanying; Wang, Yalan; Rout, Kumar Ranjan; Fuglerud, Terje; Chen, De (Peer reviewed; Journal article, 2020)The comprehensive kinetic study for CuCl2/γ-Al2O3-based catalysts was performed to elucidate the co-promoter effect in the ethylene oxychlorination, one of the most significant industrial processes to produce vinyl chloride ... -
Unraveling Enhanced Activity, Selectivity, and Coke Resistance of Pt–Ni Bimetallic Clusters in Dry Reforming
Niu, Juntian; Wang, Yalan; Liland, Shirley Elisabeth Sjø; Regli, Samuel K.; Yang, Jia; Rout, Kumar Ranjan; Luo, Jun; Rønning, Magnus; Ran, Jingyu; Chen, De (Peer reviewed; Journal article, 2021)By introducing Pt atoms into the surface of reduced hydrotalcite (HT)-derived nickel (Ni/HT) catalysts by redox reaction, we synthesized an enhanced active and stable Ni-based catalyst for methane dry reforming reaction. ...